Product ID:AA 3-007 SOLVENT BLEND
MSDS Date:01/26/1998
FSC:8010
NIIN:01-441-5940
Status Code:A
MSDS Number: CLMYL

ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC

3849 FISHER RD
COLUMBUS, OH 43216
US

Emergency Phone: 1-800-274-5263

Info Phone: 614-790-3333 / 800-325-3751

Preparer: ERNEST CARTER

Cage: 7L600

ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC

2219 COLUMBUS, OH 43216 US

Telephone: 614-790-3333 / 800-325-3751

Cage: 7L600

ALIPHATIC PETROLEUM DISTILLATES

CAS: 64742-89-8

ISOBUTYL ISOBUTYRATE

CAS: 97-85-8

RTECS: NQ5250000

ISOPROPANOL

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 980 MG/M3;400 PPM

ACGIH TLV: 983 MG/M3;400 PPM

ETHYL ACETATE

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 1400 MG/M3;400 PPM

ACGIH TLV: 1440 MG/M3;400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYE: MAY CAUSE EYE IRRITATION. MAY
INCLUDE STINGING, TEARING, REDNESS.AND SWELLING OF EYES. SKIN:
MAY CAUSE MILD SKIN IRRITATION.PROLONGED OR REPEATED CONTACT MAY
DRY THE SKIN, SYMPTOMS MAY IN CLUDE REDNESS, BURNING, DRYING
AND CRACKING,OF SKIN, AND SKIN BURNS.PASSAGE OF THIS MATERIAL INTO
THE BODY THROUGH THE SKIN IS POSSIBLE,BUT IT IS UNLIKELY THAT THIS
WOULD RESULT IN HARMFUL EFFECTS DUR ING SAFE HANDLING AND
USE.SWALLOWING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL
HANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS.
INHALATION:BREATHING IN SMALL AMOUNTS NOT LIKELY TO CAUSE HARM.
Effects of Overexposure:SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL
THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE MATERIAL
THROUGH THE SKIN MAY INCLUDE: STOMACH OR INTESTINAL UPSET (NAUSEA,
VOMITING, DIARRHEA) IRR ITATION (NOSE, THROAT, AIRWAYS), CENTRAL
NERVOUS SYSTEM DEPRESSION (DIZZINESS, DROWSINESS, WEAKNESS,
FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS), LOW BLOOD PRESSURE,
MILD, TEMPORARY CHANGES IN THE LIV ER, EFFECTS ON HEART RATE,
RESPIRATORY DEPRESSION (SLOWING OF THE BREATHING RATE), LOSS OF
COORDINATION, CONFUSION, LUNG EDEMA (FLUID BUILD UP IN THE LUNG
TISSUE). KIDNEY DAMAGE, COMA.

First Aid:EYES: FLUSH EYES GENTLY WITH WATER FOR AT LEAST 15MINUTES
WHILE HOLDING EYELIDS APART.SEEK IMMEDIATE MEDICAL
ATTENTION.SKIN:REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH
SOAP AND WATER.IF SYMP TOMS PERSIST, SEEK MEDICAL ATTENTION.LAUNDER
CLOTHING BEFORE REUSE. SWALLOWING: SEEK MEDICAL ATTENTION.IF
INDIVIDUAL IS DROWSY OR UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH;
PLACE INDIVIDUAL ON LEFT S IDE WITH THE HEAD DOWN. CONSULT A
PHYSICIAN. INHALATION:IF SYMPTOMS DEVELOP, MOVE INDIVIDUAL AWAY
FROM EXPOSURE AND INTO FRESH AIR. SEEK MEDICALN ATTENTION.

Flash Point Method:TCC
Flash Point:=-6.5C, 20.F
Lower Limits:.9%
Extinguishing Media:REGULAR FOAM, WATER FOG, CARBON DIOXIDE, DRY
CHEMICAL.
Fire Fighting Procedures:WEAR A SELF CONTAINED BREATHING APPARATUS WITH
A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH
APPRORIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PRESONAL PROTECTIVE
EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND OR MAY BE MOVED BY VENTILATION AND IGNITED
BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC
MOTORS, STATIC. NEVER USE WELDI NG OR CUTTING TORCH ON OR NEAR DRUM
(EVEN EMPTY) BECAUSE PRODUCT CAN IGNITE EXPLOSIVELY. MAY FORM
EXPLOSIVE PEROXIDES.

Spill Release Procedures:SMALL SPILL ABSORB LIQUID ON VERMICULITE,
FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND TRANSFER TO
HOOD.LARGE SPILL: ELIMINATE ALL IGNITION SOURCES(FLARES, FLAMES,
INCLUDING PILOT LIGHTS, ELECTRIC AL SPARKS), PERSONS NOT WEARING
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA STOP SPILL AT
SOURCE. PUMP OR VACUUM TRANSFER SPILLED PRODUCT TO CLEAN CONTAINERS
FOR RECOVERY.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS
GIVEN IN THE DATA SHEET MUST BE OBSERV ED. ALL FIVE GALLON PAILS
AND LARGER CONTAINERS SHOULD BE GROUNDED. SAFETY SHOWERS SHOULD BE
AVAILAB

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OF ANY
COMPONENT IS EXCEEDED(SEE EXPOSURE GUIDELINES), A NIOSH/MSHA
APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL. OS HA REGULATIONS ALSO PERMIT OTHER
NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED
CONDITIONS (SEE YOUR INDUSTRIAL HYGIENIST).
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:WEAR RESISTANT GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES.
Supplemental Safety and Health

Boiling Pt:=75.6C, 168.F
Vapor Pres:76.000 MMHG @ 68.00 F
Vapor Density:>1 AIR=1
Spec Gravity:.782 @ 77.00 F
VOC Pounds/Gallon:781
VOC Grams/Liter:6.5
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:LIQUID HOMOGENEOUS SOLUTION
Percent Volatiles by Volume:100.0%

Stability Indicator/Materials to Avoid:YES
ACETALDEHYDE, ACIDS, CHLORINE, ETHYLENE OXIDE ISOCYANATES, STRONG
ALKALIES, STRONG OXIDIZING AGENTS;
Stability Condition to Avoid:DO NOT USE WITH ALUMINUM EQUIPMENT AT
TEMPERATURES ABOVE 120 DEG F.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE,
VARIOUS HYDROCARBONS.
Conditions to Avoid Polymerization:WILL NOT UNDERGO.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

Toxicological Information:SILICON: LD50 (ORAL, RAT) 3160 MG/KG.
MANGANESE: LD50 (ORAL, RAT) 9,000 MG/KG. IRON: INTRAPERITONEAL
RABBIT LDL0: 20 MG/KG - NO TOXIC EFFECT NOTED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT AVAILABLE

Transport Information:CONTAINER/MODE: 55 GAL DRUM/TRUCK PACKAGE NOS
COMPONENT: NOT APPLICABLE RQ (REPORTABLE QUANTITY) -49 CFR 172.101
PRODUCT QUANTITY: (50000 LBS) COMPONENT: BENZENE

State Regulatory Information:THE FOLLOWING STATEMENT IS MADE IN ORDER
TO
COMPLY WITH THE CALIFORNIA SAFE DRINKING WATER
AND TOXIC ENFORCEMENT ACT OF 1986: